Controlling photoreactions with restricted spaces and weak intermolecular forces: exquisite selectivity during oxidation of olefins by singlet oxygen.

Forces: Exquisite Selectivity during Oxidation of Olefins by Singlet Oxygen Arunkumar Natarajan,† Lakshmi S. Kaanumalle,† Steffen Jockusch,# Corinne L. D. Gibb,‡ Bruce C. Gibb,‡ Nicholas J. Turro,# and V. Ramamurthy*,† Department of Chemistry, UniVersity of Miami, Coral Gables, Florida 33124, Department of Chemistry, Columbia UniVersity, New York, New York 10027, and Department of Chemistry, UniVersity of New Orleans, New Orleans, Louisiana 70148